Uranium speciation and stability after reductive immobilization in aquifer sediments

It has generally been assumed that the bioreduction of hexavalent uranium in groundwater systems will result in the precipitation of immobile uraninite (UO₂). In order to explore the form and stability of uranium immobilized under these conditions, we introduced lactate (15 mM for 3 months) into flow-through columns containing sediments derived from a former uranium-processing site at Old Rifle, CO. This resulted in metal-reducing conditions as evidenced by concurrent uranium uptake and iron release. Despite initial augmentation with Shewanella oneidensis, bacteria belonging to the phylum Firmicutes dominated the biostimulated columns. The immobilization of uranium (∼1 mmol U per kg sediment) enabled analysis by X-ray absorption spectroscopy (XAS). Tetravalent uranium associated with these sediments did not have spectroscopic signatures representative of U-U shells or crystalline UO₂. Analysis by microfocused XAS revealed concentrated micrometer regions of solid U(IV) that had spectroscopic signatures consistent with bulk analyses and a poor proximal correlation (μm scale resolution) between U and Fe. A plausible explanation, supported by biogeochemical conditions and spectral interpretations, is uranium association with phosphoryl moieties found in biomass; hence implicating direct enzymatic uranium reduction. After the immobilization phase, two months of in situ exposure to oxic influent did not result in substantial uranium remobilization. Ex situ flow-through experiments demonstrated more rapid uranium mobilization than observed in column oxidation studies and indicated that sediment-associated U(IV) is more mobile than biogenic UO₂. This work suggests that in situ uranium bioimmobilization studies and subsurface modeling parameters should be expanded to account for non-uraninite U(IV) species associated with biomass.     

The ammonite faunas of the Osmington Oolite Formation (Jurassic, Middle Oxfordian) of the Dorset coast

A detailed study of the lithologies of each of the beds present in the Osmington Oolite Formation of south Dorset is used to allocate numerous loose-collected ammonites to their correct stratigraphic horizons. Much new material has been collected by the author in addition to the limited amount of material available in museum collections. The age of the faunas of the three constituent members of the Osmington Oolite Formation is each assessed and placed into the context of Middle Oxfordian ammonite sequences elsewhere in England and in Europe.     

Hydro-geochemical processes in an area with saline groundwater in lower Shire River valley, Malawi: An integrated application of hierarchical cluster and principal component analyses

Our ability to adapt to changes in groundwater quality, arising from a changing climate and/or local pressures, is dependent on comprehension of the governing controls of spatial variation in groundwater chemistry. This paper presents results of an assessment of dominant hydro-geochemical processes controlling groundwater chemical composition, using an integrated application of hierarchical cluster analysis (HCA) and principal component analysis (PCA) of a major ion dataset of groundwater from lower Shire River valley, Malawi. The area is in the southernmost part of the western section of the East African Rift System (EARS) and has localised occurrence of saline groundwater. HCA classified samples into three main clusters (C1-C3) according to their dominant chemical composition: C1 (dominant composition: Na-Cl; median TDS: 3436 mg L⁻¹), C2 (dominant composition: Na-HCO₃; median TDS: 966 mg L⁻¹) and C3 (dominant composition: alkali earths-HCO₃; median TDS: 528 mg L⁻¹). These clusters were in turn described by the principal components PC1, PC3 and PC2, respectively, resulting from the PCA. The results of the PCA and geochemical interpretation suggest that the spatial variation of groundwater quality in the area is influenced by the following processes: C3 samples result mainly from H₂CO₃ weathering of aluminosilicate minerals by percolating water supersaturated with CO₂. In addition to aluminosilicate weathering, C2 samples are influenced by the processes of cation exchange of Ca²⁺ and Mg²⁺ in the water for Na⁺ on clay minerals, and carbonate precipitation. The increase in ionic strength of C2 samples is attributed to mixing with high TDS groundwater in proximity with C2 samples. The saline/brackish C1 groundwater results from the processes of evaporation (for samples with high water table close to the Shire marshes) and dissolution of Cl⁻ and SO₄-evaporative salts followed by mineralised seep from sedimentary Karoo and Cretaceous Lupata sandstones.     

Floods in megacity environments: vulnerability and coping strategies of slum dwellers in Dhaka/Bangladesh

In many megacities of the global south, the combination of rapid population growth and high pressure on space for housing, results in urban growth taking place in areas particularly prone to natural hazards. Dhaka, the capital of Bangladesh, is no exception to this rule. Many marginal settlements or slums are located on low-lying land at high risk of flooding. This paper analyzes the vulnerability of slum dwellers in Dhaka and highlights the major factors behind their sensitivity to floods and their ability to adapt to the related changes. The empirical findings presented are based on a questionnaire survey covering 625 households in five slum areas of Dhaka. Our data suggests that social capital plays an important role with regard to the ability of slum dwellers to find ways to live with the floods. Regardless of how strongly people are affected, mutual help and support are dominant features in times of crises. While poorly educated and resourced slum dwellers are highly vulnerable to external shocks, they still show a surprising capacity to cope with natural calamities.     

双参数混合正则化方法及在电导率反演成像中的应用

通过引入带有二阶正则算子的正则化项,建立了一种双参数混合正则化方法.为确定最佳正则化参数,这里主要应用L-曲线法、偏差原理和广义交叉校验准则的优化组合来确定.首先对理论模型进行了数值模拟,通过与截断奇异值分解法、共轭梯度法及标准Tikhonov正则化法的结果比较,表明该方法不仅精度高,而且对于数据的随机扰动具有稳定性....     

新疆地区环境噪声层析成像研究

本文利用北京大学宽频带流动地震台阵和新疆地震监测台网12个月连续地震记录数据,采用环境噪声层析成像方法获得了新疆地区的周期从10～35 s范围内的瑞利面波相速度异常分布图像.研究结果与地表地质构造相一致,新疆地区的天山、两盆大地构造与瑞利面波相速度异常有较好的对应关系.短周期10～20 s的图像显示两个盆地内都呈现低速...     

Chemical fractionation in the silicate vapor atmosphere of the Earth

Despite its importance to questions of lunar origin, the chemical composition of the Moon is not precisely known. In recent years, however, the isotopic composition of lunar samples has been determined to high precision and found to be indistinguishable from the terrestrial mantle despite widespread isotopic heterogeneity in the Solar System. In the context of the giant-impact hypothesis, this level of isotopic homogeneity can evolve if the proto-lunar disk and post-impact Earth undergo turbulent mixing into a single uniform reservoir while the system is extensively molten and partially vaporized. In the absence of liquid–vapor separation, such a model leads to the lunar inheritance of the chemical composition of the terrestrial magma ocean. Hence, the turbulent mixing model raises the question of how chemical differences arose between the silicate Earth and Moon. Here we explore the consequences of liquid–vapor separation in one of the settings relevant to the lunar composition: the silicate vapor atmosphere of the post-giant-impact Earth. We use a model atmosphere to quantify the extent to which rainout can generate chemical differences by enriching the upper atmosphere in the vapor, and show that plausible parameters can generate the postulated enhancement in the FeO/MgO ratio of the silicate Moon relative to the Earth's mantle. Moreover, we show that liquid–vapor separation also generates measurable mass-dependent isotopic offsets between the silicate Earth and Moon and that precise silicon isotope measurements can be used to constrain the degree of chemical fractionation during this earliest period of lunar history. An approach of this kind has the potential to resolve long-standing questions on the lunar chemical composition.     

Comparing gravity and gravity gradient surveys

Noise levels in marine and airborne full tensor gravity gradiometer surveys together with conventional land, marine and airborne gravity surveys are estimated and analysed in gridded form, resulting in relations that detail how these different survey systems can be compared analytically. After defining survey parameters including line spacing, speed and instrument bandwidth, the relations estimate the noise levels that result on either grids of gravity (gz) or gravity gradient (Gzz) as a function of the spatial filtering often applied during geological interpretation. Such comparisons are believed to be a useful preliminary guide for survey selection and planning.     

Evaluation of the 15 July 2009 Fiordland,New Zealand Tsunami in the Source Region

We undertake detailed near-field numerical modelling of the tsunami generated by the 15 July 2009 earthquake (Mw 7.8) in Fiordland, New Zealand. High resolution bathymetry and topography data at Breaksea and Dusky Sounds, and Chalky and Preservation Inlets are derived mostly from digitised New Zealand nautical charts, Shuttle Radar Topographic Mission (SRTM) 3 arc-second data, and General Bathymetric Chart of the Ocean (GEBCO) 30 s data. A combination of continuous and campaign Global Positioning System (GPS), satellite radar (ALOS/PALSAR InSAR images) and seismology data are used to constrain the seafloor deformation for the initial tsunami condition. This source model, derived independently of DART observations, provides an excellent fit to observed tsunami elevations recorded by DART buoy 55015. The model results in the near field show maximum tsunami elevations in the range 0.5–2.0 m inside the sounds and inlets with maximum flow speeds of 3.0 m/s. Along the open coast, maximum tsunami elevations reach 2.0 m. The high flow speeds through the inlets may change the inlet stratifications and water mass inside the sounds. Media reports and field reconnaissance data show some tsunami evidence at Cormorant Cove, Duck and Goose Coves, and Passage Point.     

Implementation of a second‐order paraxial boundary condition for a water‐saturated layered half‐space in plane strain

A half‐space finite element and a transmitting boundary are developed for a water‐saturated layered half‐space using a paraxial boundary condition. The exact dynamic stiffness of a half‐space in plane strain is derived and a second‐order paraxial approximation of the stiffness is obtained. A half‐space finite element and a transmitting boundary are then formulated. The development is verified by comparison of the dynamic stiffness of impermeable and permeable rigid strip foundations with other published results. The advantage of using the paraxial boundary condition in comparison with the rigid boundary condition is examined. It is shown that the paraxial boundary condition offers significant gain and the resulting half‐space finite element and transmitting boundary can represent the effects of a water‐saturated layered half‐space with good accuracy and efficiency. In addition, the numerical method described herein maintains the strengths and advantages of the finite element method and can be easily applied to demanding problems of soil–structure interaction in a water‐saturated layered half‐space. Copyright © 2010 John Wiley & Sons, Ltd.